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                ID:  

                PW:

                ProductsYour location:Products

                Nickel Sulfate

                MSDS Number: KWC-010
                Effective Date: NOV.16,2004

                1. Product Identification
                Synonyms : Nickel (II) sulfate hexahydrate (1:1:6); sulfuric acid, nickel (2+) salt, hexahydrate
                CAS No. : 7786-81-4 Anhydrous; 10101-97-0 Hexahydrate
                Molecular Weight : 262.86
                Chemical Formula : NiSO4 . 6H2O

                2. Composition/Information on Ingredients

                Ingredient
                CAS No
                Percent
                Hazardous
                Nickel Sulfate Hexahydrate
                10101-97-0
                Ni22%
                Yes

                3. Hazards Identification
                Emergency Overview
                WARNING! HARMFUL IF SWALLOWED OR INHALED. CAUSES IRRITATION TO SKIN, EYES AND RESPIRATORY TRACT. MAY CAUSE ALLERGIC SKIN OR RESPIRATORY REACTION. CANCER HAZARD. CAN CAUSE CANCER. Risk of cancer depends on duration and level of exposure.
                HEBEI KINGWAY CHEMICAL INDUSTRY CO., LTD. Ratings (Provided here for your convenienc)

                Health Rating:
                3 - Severe (Cancer Causing)
                Flammability Rating :
                0 - None
                Reactivity Rating :
                0 - None
                Contact Rating :
                3 - Severe (Life)
                Lab Protective Equip :
                GOGGLES; LAB COAT; VENT HOOD; PROPER GLOVES
                Storage Color Code :
                Blue (Health)

                Potential Health Effects
                Inhalation:
                Causes irritation to the respiratory tract. Symptoms may include coughing, sore throat, and shortness of breath. Lung damage may result from a single high exposure or lower repeated exposures. Lung allergy occasionally occurs, with asthma type symptoms.
                Ingestion:
                Toxic. Symptoms may include abdominal pain, diarrhea, nausea, and vomiting. Absorption is poor, but should it occur, symptoms may include giddiness, capillary damage, myocardial weakness, central nervous system depression, and kidney and liver damage.
                Skin Contact:
                Causes irritation. May cause skin allergy with itching, redness or rash. Some individuals may become sensitized to the substance and suffer "nickel itch", a form of dermatitis.
                Eye Contact:
                Causes irritation, redness, and pain.
                Chronic Exposure:
                Prolonged or repeated exposure to excessive concentrations may affect lungs, liver and kidneys. Chronic exposure to nickel and nickel compounds is associated with cancer.
                Aggravation of Pre-existing Conditions:
                Persons with pre-existing skin disorders, impaired respiratory or pulmonary function, or with a history of asthma, allergies, or sensitization to nickel compounds may be at an increased risk upon exposure to this substance.

                4. First Aid Measures
                Inhalation:
                Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention.
                Ingestion:
                Induce vomiting immediately as directed by medical personnel. Never give anything by mouth to an unconscious person. Get medical attention.
                Skin Contact:
                Wipe off excess material from skin then immediately flush skin with plenty of water for at least 15 minutes. Remove contaminated clothing and shoes. Get medical attention. Wash clothing before reuse. Thoroughly clean shoes before reuse.
                Eye Contact:
                Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids occasionally. Get medical attention immediately.

                5. Fire Fighting Measures
                Fire : ot considered to be a fire hazard.
                Explosion : Not considered to be an explosion hazard.
                Fire Extinguishing Media : Use any means suitable for extinguishing surrounding fire.
                Special Information:
                In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full facepiece operated in the pressure demand or other positive pressure mode.

                6. Accidental Release Measures
                Ventilate area of leak or spill. Wear appropriate personal protective equipment as specified in Section 8. Spills: Sweep up and containerize for reclamation or disposal. Vacuuming or wet sweeping may be used to avoid dust dispersal. US Regulations (CERCLA) require reporting spills and releases to soil, water and air in excess of reportable quantities. The toll free number for the US Coast Guard National Response Center is (800) 424-8802.

                7. Handling and Storage
                Keep in a tightly closed container, stored in a cool, dry, ventilated area. Protect against physical damage. Isolate from incompatible substances. Areas in which exposure to nickel metal or soluble nickel compounds may occur should be identified by signs or appropriate means, and access to the area should be limited to authorized persons. Wear special protective equipment (Sec. 8) for maintenance break-in or where exposures may exceed established exposure levels. Wash hands, face, forearms and neck when exiting restricted areas. Shower, dispose of outer clothing, change to clean garments at the end of the day. Avoid cross-contamination of street clothes. Wash hands before eating and do not eat, drink, or smoke in workplace. Containers of this material may be hazardous when empty since they retain product residues (dust, solids); observe all warnings and precautions listed for the product.

                8. Exposure Controls/Personal Protection
                Airborne Exposure Limits:
                OSHA Permissible Exposure Limit (PEL): soluble Nickel compounds as Ni: 1 mg/m3 (TWA) ACGIH Threshold Limit Value (TLV): soluble Nickel compounds as Ni: 0.1 mg/m3 (TWA)
                Ventilation System:
                A system of local and/or general exhaust is recommended to keep employee exposures below the Airborne Exposure Limits. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area. Please refer to the ACGIH document, Industrial Ventilation, A Manual of Recommended Practices, most recent edition, for details.
                Personal Respirators (NIOSH Approved):
                If the exposure limit is exceeded, a half-face dust/mist respirator may be worn for up to ten times the exposure limit or the maximum use concentration specified by the appropriate regulatory agency or respirator supplier, whichever is lowest. A full-face piece dust/mist respirator may be worn up to 50 times the exposure limit, or the maximum use concentration specified by the appropriate regulatory agency, or respirator supplier, whichever is lowest. For emergencies or instances where the exposure levels are not known, use a full-facepiece positive-pressure, air-supplied respirator. WARNING: Air-purifying respirators do not protect workers in oxygen-deficient atmospheres.
                Skin Protection:
                Rubber or neoprene gloves and additional protection including impervious boots, apron, or coveralls, as needed in areas of unusual exposure.
                Eye Protection:
                Use chemical safety goggles and/or full face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area.
                Other Control Measures:
                Eating, drinking, and smoking should not be permitted in areas where solids or liquids containing soluble nickel compounds are handled, processed, or stored. NIOSH recommends pre-placement and periodic medical exams, with maintaining of records for all employees exposed to nickel in the workplace.

                9. Physical and Chemical Properties

                Appearance :
                Blue-green crystals
                Odor :
                Odorless
                Solubility :
                75.6 g/100 cc water @ 15.5C
                Specific Gravity:
                2.03
                Ph :
                ca. 4.5
                % Volatiles by volume @ 21C (70F) :
                0
                Boiling Point :
                103C (217F) (Loses 6H2O)
                Melting Point :
                100C (212F) Loses water
                Vapor Density (Air=1) :
                No information found
                Vapor Pressure (mm Hg) :
                No information found
                Evaporation Rate (BuAc=1) :
                No information found

                10. Stability and Reactivity
                Stability:
                Stable under ordinary conditions of use and storage. At 53.3C (128F), the substance undergoes transition to transparent green crystals. Solutions are acidic.
                Hazardous Decomposition Products: Burning may produce sulfur oxides.
                Hazardous Polymerization: Will not occur.
                Incompatibilities: Strong acids.
                Conditions to Avoid:

                11. Toxicological Information
                No LD50/LC50 information found relating to normal routes of occupational exposure. Investigated as a tumorigen and mutagen.

                Ingredient
                Known
                Anticipated
                IARC Category
                Nickel Sulfate Hexahydrate(10101-97-0)
                No
                Yes
                1

                12. Ecological Information
                Environmental Fate : No information found.
                Environmental Toxicity : No information found.

                13. Disposal Considerations
                Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste disposal facility. Processing, use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Dispose of container and unused contents in accordance with federal, state and local requirements.

                14. Transport Information
                Domestic (Land, D.O.T.)
                Proper Shipping Name : RQ, ENVIRONMENTALLY HAZARDOUS SUBSTANCES, SOLID, N.O.S. (NICKEL SULFATE)
                Hazard Class : 9
                UN/NA : UN3077
                Packing Group : III
                Information reported for product/size : 100LB

                15. Regulatory Information

                Chemical Inventory Status - Part 1

                Ingredient
                TSCA
                EC
                Japan
                Australia
                Nickel Sulfate Hexahydrate(10101-97-0)
                Yes
                Yes
                Yes
                Yes

                Chemical Inventory Status - Part 2

                Ingredient
                Canada
                Korea
                DSL
                DSL
                Nickel Sulfate Hexahydrate(10101-97-0)
                Yes
                Yes
                Yes
                No

                Chemical Weapons Convention: No TSCA 12(b): No CDTA: No
                SARA 311/312: Acute: Yes Chronic: Yes Fire: No Pressure: No
                Reactivity: No (Mixture / Solid)
                Prop 65:
                THIS PRODUCT CONTAINS A CHEMICAL(S) KNOWN TO THE STATE OF CALIFORNIA TO CAUSE CANCER.
                Australian Hazchem Code : 2[Z]
                Poison Schedule : S6
                WHMIS:
                This MSDS has been prepared according to the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all of the information required by the CPR.

                16. Other Information
                NFPA Ratings: Health: 2 Flammability: 0 Reactivity: 0
                Label Hazard Warning:
                WARNING! HARMFUL IF SWALLOWED OR INHALED. CAUSES IRRITATION TO SKIN, EYES AND RESPIRATORY TRACT. MAY CAUSE ALLERGIC SKIN OR RESPIRATORY REACTION. CANCER HAZARD. CAN CAUSE CANCER. Risk of cancer depends on duration and level of exposure.
                Label Precautions:
                Do not get in eyes, on skin, or on clothing. Do not breathe dust. Keep container closed. Use only with adequate ventilation. Wash thoroughly after handling.
                Label First Aid:
                If swallowed, induce vomiting immediately as directed by medical personnel. Never give anything by mouth to an unconscious person. In case of contact, wipe off excess material from skin then immediately flush eyes or skin with plenty of water for at least 15 minutes. Remove contaminated clothing and shoes. Wash clothing before reuse. If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. In all cases, get medical attention.

                Disclaimer:
                Hebei Kingway Chemical Industry Co., Ltd provides the information contained herein in good faith but makes no representation as to its comprehensiveness or accuracy. This document is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. Individuals receiving the information must exercise their independent judgment in determining its appropriateness for a particular purpose. HeBei Kingway Chemical Industry Co., Ltd. makes no representations or warranties, either express or implied, including without limitation any warranties of merchantability, fitness for a particular purpose with respect to the information set forth herein or the product to which the information refers. accordingly, HeBei Kingway Chemical Industry Co., Ltd. will not be responsible for damages resulting from use of or reliance upon this information.


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